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| <import namespace="http://fasb.org/us-types/2019-01-31" schemaLocation="http://xbrl.fasb.org/us-gaap/2019/elts/us-types-2019-01-31.xsd"/> |
| <import namespace="http://www.xbrl.org/dtr/type/non-numeric" schemaLocation="http://www.xbrl.org/dtr/type/nonNumeric-2009-12-16.xsd"/> |
| <import namespace="http://www.xbrl.org/dtr/type/numeric" schemaLocation="http://www.xbrl.org/dtr/type/numeric-2009-12-16.xsd"/> |
| <import namespace="http://xbrl.sec.gov/country/2017-01-31" schemaLocation="https://xbrl.sec.gov/country/2017/country-2017-01-31.xsd"/> |
| <import namespace="http://xbrl.sec.gov/invest/2013-01-31" schemaLocation="http://xbrl.sec.gov/invest/2013/invest-2013-01-31.xsd"/> |
| <import namespace="http://fasb.org/srt/2019-01-31" schemaLocation="http://xbrl.fasb.org/srt/2019/elts/srt-2019-01-31.xsd"/> |
| <import namespace="http://fasb.org/srt-types/2019-01-31" schemaLocation="http://xbrl.fasb.org/srt/2019/elts/srt-types-2019-01-31.xsd"/> |
| <element id="pnat_CommonStockIssuedForServices" name="CommonStockIssuedForServices" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_DerivativeLiabilityExtinguishedOnConversion" name="DerivativeLiabilityExtinguishedOnConversion" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForDeferredCompensation" name="CommonStockIssuedForDeferredCompensation" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_DebtDiscountForNewIssuancesDueToDerivativeFeatureOfConvertibleNote" name="DebtDiscountForNewIssuancesDueToDerivativeFeatureOfConvertibleNote" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForConvertibleNotePayableAndAccruedInterest" name="CommonStockIssuedForConvertibleNotePayableAndAccruedInterest" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedToExtendDueDateOfConvertibleDebtValue" name="CommonStockIssuedToExtendDueDateOfConvertibleDebtValue" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedToExtendDueDateOfConvertibleDebtShares" name="CommonStockIssuedToExtendDueDateOfConvertibleDebtShares" nillable="true" xbrli:periodType="duration" type="xbrli:sharesItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ScheduleOfConvertibleNotesPayableTableTextBlock" name="ScheduleOfConvertibleNotesPayableTableTextBlock" nillable="true" xbrli:periodType="duration" type="nonnum:textBlockItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConversionFeatureOnConvertibleNotesAndWarrants" name="ConversionFeatureOnConvertibleNotesAndWarrants" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ReclassToEquityDueToConversions" name="ReclassToEquityDueToConversions" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_FairValueMarkToMarketAdjustments" name="FairValueMarkToMarketAdjustments" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_PrincipalNoteBalance" name="PrincipalNoteBalance" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_WarrantsIssued" name="WarrantsIssued" nillable="true" xbrli:periodType="duration" type="xbrli:sharesItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_IssuanceOfNewConvertibleNotesForCash" name="IssuanceOfNewConvertibleNotesForCash" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_IssuanceOfNewConvertibleNotesForPenalty" name="IssuanceOfNewConvertibleNotesForPenalty" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_RepaymentOfConvertibleNotesInCash" name="RepaymentOfConvertibleNotesInCash" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertedIntoSharesOfCommonStock" name="ConvertedIntoSharesOfCommonStock" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_DebtDiscountOnNewNotes" name="DebtDiscountOnNewNotes" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_SharebasedCompensationSharesAuthorizedUnderStockOptionPlansExercisePriceRangeOutstandingOptionsWeightedAverageRemainingContractualTerm2Beginning" name="SharebasedCompensationSharesAuthorizedUnderStockOptionPlansExercisePriceRangeOutstandingOptionsWeightedAverageRemainingContractualTerm2Beginning" nillable="true" xbrli:periodType="duration" type="xbrli:durationItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForNotesPrincipalAndAccruedInterestConversionsShares" name="CommonStockIssuedForNotesPrincipalAndAccruedInterestConversionsShares" nillable="true" xbrli:periodType="duration" type="xbrli:sharesItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForConvertibleNotesPayable" name="CommonStockIssuedForConvertibleNotesPayable" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForAccruedInterest" name="CommonStockIssuedForAccruedInterest" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_UnamortizedStockOptionExpense" name="UnamortizedStockOptionExpense" nillable="true" xbrli:periodType="instant" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableTextBlock" name="ConvertibleNotePayableTextBlock" nillable="true" xbrli:periodType="duration" type="nonnum:textBlockItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_AccruedInterest" name="AccruedInterest" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForNotesPrincipalConversionsShares" name="CommonStockIssuedForNotesPrincipalConversionsShares" nillable="true" xbrli:periodType="duration" type="xbrli:sharesItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForNotesPrincipalConversionsValue" name="CommonStockIssuedForNotesPrincipalConversionsValue" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForServicesAndDeferredCompensationShares" name="CommonStockIssuedForServicesAndDeferredCompensationShares" nillable="true" xbrli:periodType="duration" type="xbrli:sharesItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_CommonStockIssuedForServicesAndDeferredCompensationValue" name="CommonStockIssuedForServicesAndDeferredCompensationValue" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_DerivativeLiabilitiesExtinguishedOnConversion" name="DerivativeLiabilitiesExtinguishedOnConversion" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" type="xbrli:monetaryItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_WarrantExercisePrice" name="WarrantExercisePrice" nillable="true" xbrli:periodType="duration" type="num:perShareItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_RobertLeeMember" name="RobertLeeMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ShareholdersMember" name="ShareholdersMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotesMember" name="ConvertibleNotesMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_AdvancedInnovativeRecoveryTechnologiesMember" name="AdvancedInnovativeRecoveryTechnologiesMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_B3Member" name="B3Member" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_FourOfficersMember" name="FourOfficersMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_AirTechMember" name="AirTechMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableOneMember" name="ConvertibleNotePayableOneMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableTwoMember" name="ConvertibleNotePayableTwoMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableThreeMember" name="ConvertibleNotePayableThreeMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableFourMember" name="ConvertibleNotePayableFourMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableFiveMember" name="ConvertibleNotePayableFiveMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableSixMember" name="ConvertibleNotePayableSixMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableSevenMember" name="ConvertibleNotePayableSevenMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableEightMember" name="ConvertibleNotePayableEightMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableNineMember" name="ConvertibleNotePayableNineMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableTenMember" name="ConvertibleNotePayableTenMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableElevenMember" name="ConvertibleNotePayableElevenMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ConvertibleNotePayableTwelveMember" name="ConvertibleNotePayableTwelveMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_NotesPayableMember" name="NotesPayableMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_NotesPayableTwoMember" name="NotesPayableTwoMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_NotesPayableThreeMember" name="NotesPayableThreeMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_NotesPayableFourMember" name="NotesPayableFourMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_EmployeesAndConsultantsMember" name="EmployeesAndConsultantsMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_FirstCustomerMember" name="FirstCustomerMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_SecondCustomerMember" name="SecondCustomerMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_ThirdCustomerMember" name="ThirdCustomerMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_FourthCustomerMember" name="FourthCustomerMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_OneVendorMember" name="OneVendorMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_FifthCustomerMember" name="FifthCustomerMember" nillable="true" xbrli:periodType="duration" type="nonnum:domainItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_DocumentAndEntityInformationAbstract" name="DocumentAndEntityInformationAbstract" abstract="true" nillable="true" xbrli:periodType="duration" type="xbrli:stringItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_NotesToFinancialStatementsAbstract" name="NotesToFinancialStatementsAbstract" abstract="true" nillable="true" xbrli:periodType="duration" type="xbrli:stringItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_YearsEndingDecember31Abstract" name="YearsEndingDecember31Abstract" abstract="true" nillable="true" xbrli:periodType="duration" type="xbrli:stringItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_WeightedAverageRemainingContracturalTermAbstract" name="WeightedAverageRemainingContracturalTermAbstract" abstract="true" nillable="true" xbrli:periodType="duration" type="xbrli:stringItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_WeightedAverageContracturalTermGrant" name="WeightedAverageContracturalTermGrant" nillable="true" xbrli:periodType="duration" type="xbrli:durationItemType" substitutionGroup="xbrli:item"/> |
| <element id="pnat_AggregateIntrinsicValueAbstract" name="AggregateIntrinsicValueAbstract" abstract="true" nillable="true" xbrli:periodType="duration" type="xbrli:stringItemType" substitutionGroup="xbrli:item"/> |
| </schema> |